2025-04-18T17:30:34

src/AnalysTool.pro

@@ -25,6 +25,7 @@ SOURCES += \
     global.cpp \
     logger/logger.cpp \
     ui/aboutform.cpp \
+    ui/coefficientselectionform.cpp \
     ui/enthalpydatacorrectionform.cpp \
     ui/rightwidget.cpp \
     thirdparty/easylogging/easylogging++.cc \
@@ -55,6 +56,7 @@ HEADERS += \
     defines.h \
     logger/logger.h \
     ui/aboutform.h \
+    ui/coefficientselectionform.h \
     ui/enthalpydatacorrectionform.h \
     ui/rightwidget.h \
     thirdparty/easylogging/easylogging++.h \
@@ -79,6 +81,7 @@ HEADERS += \
 FORMS += \
     mainwindow.ui \
     ui/aboutform.ui \
+    ui/coefficientselectionform.ui \
     ui/degreeofcrystallinityform.ui \
     ui/degreeofcureform.ui \
     ui/enthalpydatacorrectionform.ui \

src/data/pointcalculate.cpp

@@ -2,6 +2,8 @@
 
 #include "pointcalculate.h"
 #include "logger.h"
+#include "global.h"
+#include "confighandler.h"
 
 QVector<Global::ExperimentData>PointCalculate:: _dataVtr;
 QPointF PointCalculate::_peakPoint;
@@ -246,8 +248,31 @@ float PointCalculate::calculateArea() {
         integral += std::abs(cellArea);
     }
 
+    /*
+     * H = K * S / w;
+     */
+    float coefficient = 0.0f;
+    if(Global::_enthalpyCoefficientEnableFlag){
+        float startTemp = _leftSelectedPoint.x();
 
-    return integral;
+        float value1 = Global::_enthalpyCoefficientVtr.at(0);
+        float value2 = Global::_enthalpyCoefficientVtr.at(0);
+        float value3 = Global::_enthalpyCoefficientVtr.at(0);
+
+        coefficient = value1 * startTemp * startTemp +
+                value2 * startTemp +
+                value3;
+
+    }else{
+        coefficient = ConfigHandler::_configMap[ConInstrumentCoefficientStr].toFloat();
+    }
+
+    logde<<"coefficient:"<<coefficient;
+
+    float weight = 1.0f;
+    float area = integral * coefficient / weight;
+
+    return area;
 }
 
 QPair<QPointF, QPointF> PointCalculate::calculateStartAndEndPoint()

src/global.cpp

@@ -7,6 +7,9 @@ QVector<CurveFileData> _curveFileDataVtr;
 
 ExperimentInfo _experimentInfo;
 QVector<CurveExperimentData> _curveExperimentDataVtr;
+
+bool _enthalpyCoefficientEnableFlag = false;
+QVector<double> _enthalpyCoefficientVtr;
 }
 
 #if 0

src/global.h

@@ -78,6 +78,12 @@ extern QVector<CurveFileData> _curveFileDataVtr;
 // Experiment setting data.
 extern ExperimentInfo _experimentInfo;
 extern QVector<CurveExperimentData> _curveExperimentDataVtr;
+
+//
+extern bool _enthalpyCoefficientEnableFlag;
+//abc
+extern QVector<double> _enthalpyCoefficientVtr;
+
 }
 
 #if 0

src/main.cpp

@@ -25,22 +25,31 @@ int main(int argc, char *argv[])
     logde<<"config,instrument coefficient:"
         <<ConfigHandler::_configMap[ConInstrumentCoefficientStr].toFloat();
 
+#if 0
     ConfigHandler::_configMap[ConInstrumentCoefficientStr] = 2.001f;
 
     ConfigHandler::writer(false);
     ConfigHandler::reader();
     logde<<"config,instrument coefficient:"
         <<ConfigHandler::_configMap[ConInstrumentCoefficientStr].toFloat();
+#endif
     //
     QApplication::setAttribute(Qt::AA_EnableHighDpiScaling); // 启用高DPI缩放
     QApplication a(argc, argv);
     a.setWindowIcon(QIcon(":/images/logo.png"));
 
+#if 1
     MainWindow w;
     w.setWindowTitle("Analysis Tool");
     w.setWindowIcon(QIcon(":/images/logo.png"));
     w.show();
+#endif
 
+//    EnthalpyDataCorrectionForm edf;
+//    edf.show();
+
+//    CoefficientSelectionForm csf;
+//    csf.show();
 
     //    AboutForm af;
     //    af.show();

src/mainwindow.cpp

@@ -24,6 +24,7 @@ MainWindow::MainWindow(QWidget *parent)
     ,_degreeOfCrystallinityForm(new DegreeOfCrystallinityForm(this))
     ,_aboutForm(new AboutForm(this))
     ,_enthalpyDataCorrectionForm(new EnthalpyDataCorrectionForm(this))
+    ,_coefficientSelectionForm(new CoefficientSelectionForm(this))
 {
     ui->setupUi(this);
     this->setToolTip(".....");
@@ -73,6 +74,7 @@ MainWindow::MainWindow(QWidget *parent)
     setSubWidgetAttribute(_degreeOfCrystallinityForm);
     setSubWidgetAttribute(_aboutForm);
     setSubWidgetAttribute(_enthalpyDataCorrectionForm);
+    setSubWidgetAttribute(_coefficientSelectionForm);
 
     //
     setActionEnable(true);
@@ -332,7 +334,13 @@ void MainWindow::on_actionAbout_triggered()
     _aboutForm->show();
 }
 
-void MainWindow::on_actionEnthalpyCorrection_triggered()
+
+void MainWindow::on_actionEnthalpyCorrectionEdit_triggered()
 {
     _enthalpyDataCorrectionForm->show();
 }
+
+void MainWindow::on_actionEnthalpyCorrectionSelection_triggered()
+{
+    _coefficientSelectionForm->show();
+}

src/mainwindow.h

@@ -19,6 +19,7 @@
 #include "oitautoanalysisparamform.h"
 #include "aboutform.h"
 #include "enthalpydatacorrectionform.h"
+#include "coefficientselectionform.h"
 
 QT_BEGIN_NAMESPACE
 namespace Ui { class MainWindow; }
@@ -75,7 +76,9 @@ private slots:
 
     void on_actionAbout_triggered();
 
-    void on_actionEnthalpyCorrection_triggered();
+    void on_actionEnthalpyCorrectionEdit_triggered();
+
+    void on_actionEnthalpyCorrectionSelection_triggered();
 
 private:
     void connections();
@@ -98,5 +101,6 @@ private:
     OITAutoAnalysisParamForm* _OITAutoAnalysisParamForm;
     AboutForm *_aboutForm;
     EnthalpyDataCorrectionForm* _enthalpyDataCorrectionForm;
+    CoefficientSelectionForm * _coefficientSelectionForm;
 };
 #endif // MAINWINDOW_H

src/mainwindow.ui

@@ -67,7 +67,8 @@
     <property name="title">
      <string>工具</string>
     </property>
-    <addaction name="actionEnthalpyCorrection"/>
+    <addaction name="actionEnthalpyCorrectionEdit"/>
+    <addaction name="actionEnthalpyCorrectionSelection"/>
    </widget>
    <widget class="QMenu" name="menu_6">
     <property name="title">
@@ -254,9 +255,14 @@
     <string>关于</string>
    </property>
   </action>
-  <action name="actionEnthalpyCorrection">
+  <action name="actionEnthalpyCorrectionEdit">
    <property name="text">
-    <string>热焓校正</string>
+    <string>热焓校正系数编辑</string>
+   </property>
+  </action>
+  <action name="actionEnthalpyCorrectionSelection">
+   <property name="text">
+    <string>热焓校正系数选择</string>
    </property>
   </action>
  </widget>

src/ui/coefficientselectionform.cpp

@@ -0,0 +1,240 @@
+#include <QFileDialog>
+
+#include "coefficientselectionform.h"
+#include "ui_coefficientselectionform.h"
+#include "confighandler.h"
+#include "logger.h"
+#include "global.h"
+
+CoefficientSelectionForm::CoefficientSelectionForm(QWidget *parent) :
+    QWidget(parent),
+    ui(new Ui::CoefficientSelectionForm)
+{
+    ui->setupUi(this);
+
+    setWindowTitle("热焓校正系数选择");
+
+#if 1
+    ui->LineEditCoefficient->setText(
+                QString::number(
+                    ConfigHandler::_configMap[ConInstrumentCoefficientStr].toFloat(),
+                    'f',3));
+#endif
+
+    ui->radioButtonSinglePointCoefficient->setChecked(true);
+    ui->radioButtonSinglePointCoefficient->setChecked(false);
+
+    on_radioButtonSinglePointCoefficient_toggled(true);
+    on_radioButtonMultiPointCoefficient_toggled(false);
+
+    ui->textEditFileContent->setReadOnly(true);
+}
+
+CoefficientSelectionForm::~CoefficientSelectionForm()
+{
+    delete ui;
+}
+
+void CoefficientSelectionForm::on_pushButtonCalculate_clicked()
+{
+    float theory = ui->LineEditTheory->text().toFloat();
+    float measure = ui->LineEditActualMeasurement->text().toFloat();
+
+    _instrumentCoefficient = theory/measure;
+    ui->LineEditCoefficient->setText(QString::number(_instrumentCoefficient,'f',3));
+
+}
+
+void CoefficientSelectionForm::on_pushButtonConfirm_clicked()
+{
+    if(ui->radioButtonSinglePointCoefficient->isChecked()){
+        ConfigHandler::_configMap[ConInstrumentCoefficientStr] = _instrumentCoefficient;
+        ConfigHandler::writer();
+
+        Global::_enthalpyCoefficientEnableFlag = false;
+    }else{
+        QVector<double> xVtr,yVtr;
+        QJsonDocument jsonDoc = QJsonDocument::fromJson(_jsonStr.toUtf8());
+        QJsonArray jsonArray = jsonDoc.array();
+
+        for (const QJsonValue &value : jsonArray) {
+            QJsonObject jsonObj = value.toObject();
+            xVtr<<jsonObj["theory"].toDouble();
+            yVtr<<jsonObj["rate"].toDouble();
+        }
+
+        double coeff[3] = {0};
+        cubicLeastSquaresFit(xVtr.data(),yVtr.data(),xVtr.size(),coeff);
+
+        logde<<"y:"<<coeff[0]<<","
+            <<coeff[1]<<","
+           <<coeff[2];
+
+        Global::_enthalpyCoefficientEnableFlag = false;
+
+        Global::_enthalpyCoefficientVtr.clear();
+        Global::_enthalpyCoefficientVtr.push_back(coeff[2]);
+        Global::_enthalpyCoefficientVtr.push_back(coeff[1]);
+        Global::_enthalpyCoefficientVtr.push_back(coeff[0]);
+    }
+}
+
+void CoefficientSelectionForm::on_pushButtonExit_clicked()
+{
+    ui->LineEditTheory->clear();
+    ui->LineEditCoefficient->clear();
+
+    ui->labelFilePath->clear();
+    ui->textEditFileContent->clear();
+
+    _jsonStr.clear();
+
+    hide();
+}
+
+void CoefficientSelectionForm::on_pushButtonSelectFile_clicked()
+{
+    QString filePath = QFileDialog::getOpenFileName(
+                nullptr, "选择 JSON 文件", "", "JSON 文件 (*.json);;所有文件 (*.*)");
+
+    if (!filePath.isEmpty()) {
+        QFile file(filePath);
+        if (file.open(QIODevice::ReadOnly | QIODevice::Text)) {
+            QTextStream in(&file);
+            _jsonStr = in.readAll();
+            file.close();
+
+        } else {
+            qDebug() << "无法打开文件：" << filePath;
+            return;
+        }
+    } else {
+        qDebug() << "未选择文件";
+        return;
+    }
+
+    //
+    ui->labelFilePath->setText(filePath);
+    ui->textEditFileContent->setText(_jsonStr);
+}
+
+void CoefficientSelectionForm::on_radioButtonSinglePointCoefficient_toggled(bool checked)
+{
+    ui->LineEditTheory->setEnabled(checked);
+    ui->LineEditCoefficient->setEnabled(checked);
+    ui->LineEditActualMeasurement->setEnabled(checked);
+
+    ui->pushButtonCalculate->setEnabled(checked);
+#if 0
+    if(checked){
+        ui->LineEditTheory->setEnabled(true);
+        ui->LineEditCoefficient->setEnabled(true);
+        ui->LineEditActualMeasurement->setEnabled(true);
+
+        ui->pushButtonCalculate->setEnabled(true);
+    }else{
+
+        ui->LineEditTheory->setEnabled(false);
+        ui->LineEditCoefficient->setEnabled(false);
+        ui->LineEditActualMeasurement->setEnabled(false);
+
+        ui->pushButtonCalculate->setEnabled(false);
+    }
+#endif
+}
+
+void CoefficientSelectionForm::on_radioButtonMultiPointCoefficient_toggled(bool checked)
+{
+    ui->pushButtonSelectFile->setEnabled(checked);
+    ui->textEditFileContent->setEnabled(checked);
+#if 0
+    if(checked){
+        ui->pushButtonSelectFile->setEnabled(true);
+        ui->textEditFileContent->setEnabled(true);
+    }else{
+        ui->pushButtonSelectFile->setEnabled(false);
+        ui->textEditFileContent->setEnabled(false);
+    }
+#endif
+}
+
+void CoefficientSelectionForm::cubicLeastSquaresFit(
+        double x[], double y[], int n, double coeff[])
+{
+    int i, j, k;
+      double atemp[3] = {0}; // 存储x^0, x^1, x^2的和
+      double b[3] = {0};     // 右侧向量
+
+      // 计算各次幂的和
+      for (i = 0; i < n; i++) {
+          double xi = x[i];
+          double xi_pow2 = xi * xi; // x^2
+
+          // 累加atemp[0]到atemp[2]
+          atemp[0] += 1; // x^0的和等于数据点个数
+          atemp[1] += xi;
+          atemp[2] += xi_pow2;
+
+          // 计算右侧向量b
+          double yi = y[i];
+          b[0] += yi;
+          b[1] += yi * xi;
+          b[2] += yi * xi_pow2;
+      }
+
+      // 构建法方程矩阵
+      double a[3][3];
+      a[0][0] = atemp[0];
+      a[0][1] = atemp[1];
+      a[0][2] = atemp[2];
+      a[1][0] = atemp[1];
+      a[1][1] = atemp[2];
+      a[1][2] = 0;
+      a[2][0] = atemp[2];
+      a[2][1] = 0;
+      a[2][2] = 0;
+
+      // 高斯列主元消元法
+      for (k = 0; k < 2; k++) { // 消去第k列
+          // 寻找主元行
+          int max_row = k;
+          double max_val = fabs(a[k][k]);
+          for (i = k + 1; i < 3; i++) {
+              if (fabs(a[i][k]) > max_val) {
+                  max_val = fabs(a[i][k]);
+                  max_row = i;
+              }
+          }
+
+          // 交换行
+          if (max_row != k) {
+              for (j = k; j < 3; j++) {
+                  double temp = a[k][j];
+                  a[k][j] = a[max_row][j];
+                  a[max_row][j] = temp;
+              }
+              double temp_b = b[k];
+              b[k] = b[max_row];
+              b[max_row] = temp_b;
+          }
+
+          // 消元
+          for (i = k + 1; i < 3; i++) {
+              double factor = a[i][k] / a[k][k];
+              for (j = k; j < 3; j++) {
+                  a[i][j] -= factor * a[k][j];
+              }
+              b[i] -= factor * b[k];
+          }
+      }
+
+      // 回代求解
+      coeff[2] = b[2] / a[2][2];
+      for (i = 1; i >= 0; i--) {
+          double sum = 0.0;
+          for (j = i + 1; j < 3; j++) {
+              sum += a[i][j] * coeff[j];
+          }
+          coeff[i] = (b[i] - sum) / a[i][i];
+      }
+}

src/ui/coefficientselectionform.h

@@ -0,0 +1,35 @@
+#ifndef COEFFICIENTSELECTIONFORM_H
+#define COEFFICIENTSELECTIONFORM_H
+
+#include <QWidget>
+
+namespace Ui {
+class CoefficientSelectionForm;
+}
+
+class CoefficientSelectionForm : public QWidget
+{
+    Q_OBJECT
+
+public:
+    explicit CoefficientSelectionForm(QWidget *parent = nullptr);
+    ~CoefficientSelectionForm();
+
+private slots:
+    void on_radioButtonSinglePointCoefficient_toggled(bool checked);
+    void on_radioButtonMultiPointCoefficient_toggled(bool checked);
+
+    void on_pushButtonCalculate_clicked();
+    void on_pushButtonSelectFile_clicked();
+
+    void on_pushButtonConfirm_clicked();
+    void on_pushButtonExit_clicked();
+private:
+    void cubicLeastSquaresFit(double x[], double y[], int n, double coeff[4]);
+
+    QString _jsonStr;
+    Ui::CoefficientSelectionForm *ui;
+    float _instrumentCoefficient;
+};
+
+#endif // COEFFICIENTSELECTIONFORM_H

src/ui/coefficientselectionform.ui

@@ -0,0 +1,200 @@
+<?xml version="1.0" encoding="UTF-8"?>
+<ui version="4.0">
+ <class>CoefficientSelectionForm</class>
+ <widget class="QWidget" name="CoefficientSelectionForm">
+  <property name="geometry">
+   <rect>
+    <x>0</x>
+    <y>0</y>
+    <width>543</width>
+    <height>351</height>
+   </rect>
+  </property>
+  <property name="windowTitle">
+   <string>Form</string>
+  </property>
+  <widget class="QGroupBox" name="groupBox">
+   <property name="geometry">
+    <rect>
+     <x>10</x>
+     <y>40</y>
+     <width>221</width>
+     <height>111</height>
+    </rect>
+   </property>
+   <property name="title">
+    <string>参数</string>
+   </property>
+   <widget class="QWidget" name="formLayoutWidget">
+    <property name="geometry">
+     <rect>
+      <x>10</x>
+      <y>30</y>
+      <width>201</width>
+      <height>78</height>
+     </rect>
+    </property>
+    <layout class="QFormLayout" name="formLayout">
+     <item row="0" column="0">
+      <widget class="QLabel" name="jGLabel">
+       <property name="text">
+        <string>理论熔融热焓(J/g):</string>
+       </property>
+      </widget>
+     </item>
+     <item row="0" column="1">
+      <widget class="QLineEdit" name="LineEditTheory"/>
+     </item>
+     <item row="1" column="0">
+      <widget class="QLabel" name="jGLabel_2">
+       <property name="text">
+        <string>实测熔融热焓(J/g):</string>
+       </property>
+      </widget>
+     </item>
+     <item row="1" column="1">
+      <widget class="QLineEdit" name="LineEditActualMeasurement"/>
+     </item>
+    </layout>
+   </widget>
+  </widget>
+  <widget class="QPushButton" name="pushButtonExit">
+   <property name="geometry">
+    <rect>
+     <x>400</x>
+     <y>320</y>
+     <width>80</width>
+     <height>20</height>
+    </rect>
+   </property>
+   <property name="text">
+    <string>退出</string>
+   </property>
+  </widget>
+  <widget class="QRadioButton" name="radioButtonMultiPointCoefficient">
+   <property name="geometry">
+    <rect>
+     <x>250</x>
+     <y>10</y>
+     <width>91</width>
+     <height>18</height>
+    </rect>
+   </property>
+   <property name="text">
+    <string>多点系数</string>
+   </property>
+  </widget>
+  <widget class="QGroupBox" name="groupBox_2">
+   <property name="geometry">
+    <rect>
+     <x>10</x>
+     <y>170</y>
+     <width>221</width>
+     <height>81</height>
+    </rect>
+   </property>
+   <property name="title">
+    <string>计算结果</string>
+   </property>
+   <widget class="QWidget" name="formLayoutWidget_2">
+    <property name="geometry">
+     <rect>
+      <x>10</x>
+      <y>30</y>
+      <width>191</width>
+      <height>41</height>
+     </rect>
+    </property>
+    <layout class="QFormLayout" name="formLayout_2">
+     <item row="0" column="0">
+      <widget class="QLabel" name="kLabel">
+       <property name="text">
+        <string>仪器系数 K:</string>
+       </property>
+      </widget>
+     </item>
+     <item row="0" column="1">
+      <widget class="QLineEdit" name="LineEditCoefficient"/>
+     </item>
+    </layout>
+   </widget>
+  </widget>
+  <widget class="QRadioButton" name="radioButtonSinglePointCoefficient">
+   <property name="geometry">
+    <rect>
+     <x>20</x>
+     <y>10</y>
+     <width>91</width>
+     <height>18</height>
+    </rect>
+   </property>
+   <property name="text">
+    <string>单点系数</string>
+   </property>
+  </widget>
+  <widget class="QPushButton" name="pushButtonConfirm">
+   <property name="geometry">
+    <rect>
+     <x>290</x>
+     <y>320</y>
+     <width>80</width>
+     <height>20</height>
+    </rect>
+   </property>
+   <property name="text">
+    <string>确定</string>
+   </property>
+  </widget>
+  <widget class="QPushButton" name="pushButtonCalculate">
+   <property name="geometry">
+    <rect>
+     <x>110</x>
+     <y>270</y>
+     <width>85</width>
+     <height>20</height>
+    </rect>
+   </property>
+   <property name="text">
+    <string>计算</string>
+   </property>
+  </widget>
+  <widget class="QLabel" name="labelFilePath">
+   <property name="geometry">
+    <rect>
+     <x>250</x>
+     <y>40</y>
+     <width>281</width>
+     <height>16</height>
+    </rect>
+   </property>
+   <property name="text">
+    <string>当前热焓文件：</string>
+   </property>
+  </widget>
+  <widget class="QTextEdit" name="textEditFileContent">
+   <property name="geometry">
+    <rect>
+     <x>250</x>
+     <y>90</y>
+     <width>261</width>
+     <height>221</height>
+    </rect>
+   </property>
+  </widget>
+  <widget class="QPushButton" name="pushButtonSelectFile">
+   <property name="geometry">
+    <rect>
+     <x>410</x>
+     <y>60</y>
+     <width>85</width>
+     <height>20</height>
+    </rect>
+   </property>
+   <property name="text">
+    <string>选择文件</string>
+   </property>
+  </widget>
+ </widget>
+ <resources/>
+ <connections/>
+</ui>

src/ui/enthalpydatacorrectionform.cpp

@@ -1,3 +1,11 @@
+#include <cmath>
+#include <QJsonArray>
+#include <QJsonObject>
+#include <QFile>
+#include <QJsonDocument>
+#include <QDebug>
+#include <QFileDialog>
+
 #include "enthalpydatacorrectionform.h"
 #include "ui_enthalpydatacorrectionform.h"
 
@@ -7,12 +15,11 @@ EnthalpyDataCorrectionForm::EnthalpyDataCorrectionForm(QWidget *parent) :
 {
     ui->setupUi(this);
 
-    setWindowTitle("热焓校正");
+    setWindowTitle("热焓校正参数编辑");
-
-//    ui->lineEditTheoryIn->setText("28.6");
-//    ui->lineEditTheorySn->setText("60.5");
-//    ui->lineEditTheoryBi->setText("53.3");
 
+    //    ui->lineEditTheoryIn->setText("28.6");
+    //    ui->lineEditTheorySn->setText("60.5");
+    //    ui->lineEditTheoryBi->setText("53.3");
 
 }
 
@@ -23,10 +30,160 @@ EnthalpyDataCorrectionForm::~EnthalpyDataCorrectionForm()
 
 void EnthalpyDataCorrectionForm::on_pushButtonSave_clicked()
 {
+    if(ui->checkBoxC6H12->isChecked()){
+        float theory = ui->lineEditTheoryC6H12->text().toFloat();
+        float measure = ui->lineEditMeasC6H12->text().toFloat();
 
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxHg->isChecked()){
+        float theory = ui->lineEditTheoryHg->text().toFloat();
+        float measure = ui->lineEditMeasHg->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxC6H5COOH->isChecked()){
+        float theory = ui->lineEditTheoryC6H5COOH->text().toFloat();
+        float measure = ui->lineEditMeasC6H5COOH->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxIn->isChecked()){
+        float theory = ui->lineEditTheoryIn->text().toFloat();
+        float measure = ui->lineEditMeasIn->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxSn->isChecked()){
+        float theory = ui->lineEditTheorySn->text().toFloat();
+        float measure = ui->lineEditMeasSn->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxBi->isChecked()){
+        float theory = ui->lineEditTheoryBi->text().toFloat();
+        float measure = ui->lineEditMeasBi->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxKC1O3->isChecked()){
+        float theory = ui->lineEditTheoryKC1O3->text().toFloat();
+        float measure = ui->lineEditMeasKC103->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxPb->isChecked()){
+        float theory = ui->lineEditTheoryPb->text().toFloat();
+        float measure = ui->lineEditMeasPb->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxKNO3->isChecked()){
+        float theory = ui->lineEditTheoryKNO3->text().toFloat();
+        float measure = ui->lineEditMeasKNO3->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxZn->isChecked()){
+        float theory = ui->lineEditTheoryZn->text().toFloat();
+        float measure = ui->lineEditMeasZn->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxAg2SO4->isChecked()){
+        float theory = ui->lineEditTheoryAg2SO4->text().toFloat();
+        float measure = ui->lineEditMeasAg2SO4->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxCsCl->isChecked()){
+        float theory = ui->lineEditTheoryCsC1->text().toFloat();
+        float measure = ui->lineEditMeasCsCl->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxSiO2->isChecked()){
+        float theory = ui->lineEditTheorySiO2->text().toFloat();
+        float measure = ui->lineEditMeasSiO2->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxK2SO4->isChecked()){
+        float theory = ui->lineEditTheoryK2SO4->text().toFloat();
+        float measure = ui->lineEditMeasK2SO4->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxK2CrO4->isChecked()){
+        float theory = ui->lineEditTheoryK2CrO4->text().toFloat();
+        float measure = ui->lineEditMeasK2CrO4->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxBaCO3->isChecked()){
+        float theory = ui->lineEditTheoryBaCO3->text().toFloat();
+        float measure = ui->lineEditMeasBaCO3->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxAg->isChecked()){
+        float theory = ui->lineEditTheoryAg->text().toFloat();
+        float measure = ui->lineEditMeasAg->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    if(ui->checkBoxCu->isChecked()){
+        float theory = ui->lineEditTheoryCu->text().toFloat();
+        float measure = ui->lineEditMeasCu->text().toFloat();
+
+        _theoryDataVtr.push_back({theory,theory/measure});
+    }
+    //
+    saveJson();
 }
 
 void EnthalpyDataCorrectionForm::on_pushButtonExit_clicked()
 {
     hide();
 }
+
+void EnthalpyDataCorrectionForm::saveJson()
+{
+    // 创建一个 QJsonArray 来存储数据
+    QJsonArray jsonArray;
+    for (const TheoryData &data : _theoryDataVtr) {
+        QJsonObject jsonObj;
+        jsonObj["theory"] = data.theory;
+        jsonObj["rate"] = data.rate;
+        jsonArray.append(jsonObj);
+    }
+
+    // 创建一个 QJsonDocument 并设置根数组
+    QJsonDocument doc(jsonArray);
+
+    // 打开保存文件对话框，让用户选择保存位置
+    QString fileName = QFileDialog::getSaveFileName(nullptr, "保存 JSON 文件",
+                                                    "new.json", "JSON Files (*.json)");
+    if (fileName.isEmpty()) {
+        qDebug() << "用户取消了操作";
+        return;
+    }
+
+    // 确保文件名以 .json 扩展名结尾
+    if (!fileName.endsWith(".json")) {
+        fileName.append(".json");
+    }
+
+    // 写入 JSON 数据到文件
+    QFile file(fileName);
+    if (!file.open(QIODevice::WriteOnly)) {
+        qDebug() << "无法打开文件进行写入:" << file.errorString();
+        return ;
+    }
+
+    file.write(doc.toJson(QJsonDocument::Indented));  // 以格式化的方式写入 JSON 数据
+    file.close();
+}
+
+
+

src/ui/enthalpydatacorrectionform.h

@@ -19,8 +19,15 @@ private slots:
     void on_pushButtonSave_clicked();
 
     void on_pushButtonExit_clicked();
-
 private:
+    void saveJson();
+private:
+    struct TheoryData{
+        float theory;
+        float rate;
+    };
+    QVector<TheoryData> _theoryDataVtr;
+
     Ui::EnthalpyDataCorrectionForm *ui;
 };
 

src/ui/enthalpydatacorrectionform.ui

@@ -19,7 +19,7 @@
      <x>40</x>
      <y>50</y>
      <width>431</width>
-     <height>518</height>
+     <height>520</height>
     </rect>
    </property>
    <layout class="QGridLayout" name="gridLayout">
@@ -142,9 +142,18 @@
     </item>
     <item row="0" column="3">
      <widget class="QLabel" name="label_6">
+      <property name="maximumSize">
+       <size>
+        <width>9999</width>
+        <height>22</height>
+       </size>
+      </property>
       <property name="text">
        <string>理论温度(℃)</string>
       </property>
+      <property name="alignment">
+       <set>Qt::AlignBottom|Qt::AlignHCenter</set>
+      </property>
      </widget>
     </item>
     <item row="15" column="3">
@@ -254,9 +263,18 @@
     </item>
     <item row="0" column="2">
      <widget class="QLabel" name="label_2">
+      <property name="maximumSize">
+       <size>
+        <width>9999</width>
+        <height>22</height>
+       </size>
+      </property>
       <property name="text">
        <string>标样</string>
       </property>
+      <property name="alignment">
+       <set>Qt::AlignBottom|Qt::AlignHCenter</set>
+      </property>
      </widget>
     </item>
     <item row="1" column="1">
@@ -316,9 +334,18 @@
     </item>
     <item row="0" column="5">
      <widget class="QLabel" name="label_4">
+      <property name="maximumSize">
+       <size>
+        <width>9999</width>
+        <height>22</height>
+       </size>
+      </property>
       <property name="text">
        <string>实测热焓(J/g)</string>
       </property>
+      <property name="alignment">
+       <set>Qt::AlignBottom|Qt::AlignHCenter</set>
+      </property>
      </widget>
     </item>
     <item row="16" column="2">
@@ -501,9 +528,18 @@
     </item>
     <item row="0" column="4">
      <widget class="QLabel" name="label_5">
+      <property name="maximumSize">
+       <size>
+        <width>9999</width>
+        <height>22</height>
+       </size>
+      </property>
       <property name="text">
        <string>理论热焓(J/g)</string>
       </property>
+      <property name="alignment">
+       <set>Qt::AlignBottom|Qt::AlignHCenter</set>
+      </property>
      </widget>
     </item>
     <item row="3" column="5">
@@ -592,11 +628,11 @@
     <string>退出</string>
    </property>
   </widget>
-  <widget class="QWidget" name="">
+  <widget class="QWidget" name="layoutWidget">
    <property name="geometry">
     <rect>
      <x>40</x>
-     <y>10</y>
+     <y>20</y>
      <width>344</width>
      <height>24</height>
     </rect>

src/ui/instrumentcoefficientform.cpp

@@ -14,6 +14,9 @@ InstrumentCoefficientForm::InstrumentCoefficientForm(QWidget *parent) :
                 QString::number(
                     ConfigHandler::_configMap[ConInstrumentCoefficientStr].toFloat(),
                     'f',3));
+
+    ui->LineEditTheory->text().clear();
+    ui->LineEditActualMeasurement->text().clear();
 }
 
 InstrumentCoefficientForm::~InstrumentCoefficientForm()